Background:
Glycomics is the study of carbohydrates, or glycans, within a cell, tissue, or organism. New technologies have brought the human glycome into view and are beginning to reveal the role of glycans in host-pathogen interactions. The oropharyngeal niche of Streptococcus pyogenes is rich in glycans, some implicated in innate immune responses. Using a time-course approach, we characterised the dynamic oropharyngeal glycoprofile in saliva during experimental human pharyngitis with emm75 S. pyogenes (CHIVAS-M75 study).
Methods:
Baseline, acute, and convalescent saliva samples were collected from healthy adult participants challenged with emm75 S. pyogenes. Qualitative and quantitative analysis of N- and O-glycans extracted from saliva was performed by porous graphitised carbon liquid chromatography coupled with electrospray ionisation tandem mass spectrometry (PGC-LC-ESI-MS/MS; LC-MS).
Results:
Of 145 N-glycans detected in saliva, 108 have been structurally solved or predicted from elution profiles and MS2 analyses. The majority (60%) are complex N-glycans. Preliminary time-course analyses from 3 patients reveal changes in the glycoprofile 48-hours post infection. The major change is an increase in N-glycans bearing neuraminic (sialic) acid, which has a well-recognised role in the innate immune response. This effect is mediated primarily by complex, doubly-sialylated structures.
Conclusion:
The host glycome is an important research target for efforts to understand host-pathogen interactions in streptococcal pharyngitis, and these findings will be validated in a larger cohort of human challenge trial participants. The observed sialic acid response suggests it may have an important role in triggering innate immune responses to S. pyogenes mucosal infections.